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Mww-Type Titanosilicate: Synthesis, Structural Modification and Catalytic Applications to Green Oxidations

Penned By Peng Wu
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83,737 Global Ratings
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Mww-Type Titanosilicate: Synthesis, Structural Modification and Catalytic Applications to Green Oxidations

Penned By Peng Wu
4.85 83,737 Ratings
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Editor's Note:
This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.

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Length 131 Pages
Imprint Springer
Released January 1, 2013
Identifier (ISBN) 18551507
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Peng Wu
The Mind Behind the Work
Peng Wu

Peng Wu writes contemporary fiction and has always been fascinated by character-driven stories. They hold a degree in English Literature and previously worked as an editor before transitioning to writing their own books. Peng Wu lives with their spouse and a very vocal rescue cat.

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